Now Accepting Applications for Summer 2020

Below is the flyer for the 2020 summer internship program. Also included is a graphic depicting the kinds of projects available here at the OESL.

If you are interested in applying please provide:

1) Resume

2) Cover letter indicating area of research of greatest interest to you

3) Minimum of one reference

4) List of college level science courses you have completed

Please email applications to Laura Ives at iveslaur@msu.edu.

I am looking forward to receiving your application!

West Michigan ACS Community Outreach

The West Michigan Chapter of the American Chemical Society had an amazing event and invited us to take part at Grand Valley State University.  They attempted the Guinness World Record for largest periodic table.  Many different college and high school groups selected an element and created that portion of the periodic table.  We presented posters and hosted an experiment table.

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Andrew Rajewski

Andy’s final day with our lab is Friday, October 11.  He has been researching with us for more than a year and is relocating to Ann Arbor to work for PIDC doing Research and Development for them.  He is also planning on continuing to grad school next year.

Andy has become a fantastic “synthesizer” over his year with us.  He has presented a talk at ECS in Dallas and presented posters at ACS Great Lakes and the Hope College Schaap Symposium.  He has advanced our understanding of donor/acceptor compounds for organic redox flow batteries.  But more importantly, he is a fun addition to our lab and we will miss his smile.  “Cheers” to your future Andy!

Summer 2019 Wrap-up

Thanks for a great summer and another great intern group!

After tours, poster sessions, a lot of research and a lot of ice cream, we got some good feedback for next year.  It is good to know that everyone that filled out the evaluation form would recommend the MSUBI Summer Intern program to others.  Below are some other comments we received…

What I liked most?  Doing actual relevant science!  and working with projects where I have some control over the direction, priorities and techniques…  I liked having ownership of a project, in the sense that I had to decide what direction to go in and had some guidance but also the chance to pursue avenues that caught my eye….  I liked the opportunity to work towards something with a real-life application that’s realistic and impactful.

Were expectations reasonable?  Yes, I think that like any research position progress isn’t always linear, but clear goals were set and progress was reported while suggestions were given to help toward those goals.

Was the project interesting?  Yes, it allowed me to expand my scientific knowledge by doing some inorganic synthesis and learning new electrochemical techniques.

Was the experience valuable?  Absolutely!

Kassia Symstad

The final poster highlighted is Kassia’s…

Stability testing of radical cations for energy storage applications.

Kassia Symstad, Dr. Thomas F. Guarr

Electron donor molecules must be stable in both the neutral and radical cation form to be viable as shuttles for overcharge protection in lithium ion batteries or as part of a larger donor-acceptor system for use in redox flow batteries.  In this work we report stability testing on a variety of carbazole and phenothiazine-5,5-dioxide derivatives.  Conversion of the neutral molecule to its radical cation state was accomplished either by chemical oxidation or electrolysis in a spectroelectrochemical cell.  The radical cations of these donor molecules have a differect UV-vis spectra than the neutral molecules, which provides an effective means to monitor their generation and persistence.  The voltage that resulted in the maximum rate of conversion to the radical cation form was found this way.  that voltage was them applied for a longer period of time, either in a spectroelectrochemical cell or a conventional H-cell for bulk electrolysis to effect complete conversion.  This allows the radical cation to be studied on time scales ranging from seconds to months.  These stability studies are useful for the evaluation of preliminary data from a linked donor-acceptor system in a prototype RFB cell.

Anthony Porath

We had a total of seven posters presented at the Schaap Symposium.  Our next presenter is Anthony Porath…

Building blocks for multi-electron linked systems for organic redox flow batteries

Anthony Porath, Adina Dumitrascu, Dan Henton, Jason G. Gillmore, Thomas F. Guarr

A series of redox-active compounds were synthesized and electrochemically assessed for their potential use in nonaqueous redox flow batteries (RFBs).  These include electron donating species, the donors, and electron accepting species, the acceptors.  The donor and acceptor moieties are separated with an expensive ion-exchange membrane in traditional RFBs, but when covalently-linked a simple separator is able to be utilized.  The donor/acceptor systems exist in three stable oxidation states during RFB operation: reduced (anolyte), neutral, and oxidized (catholyte) forms.  The pursuit of multi-electron redox-active species would serve to further lower costs.  Decreasing the cost as much as possible is important as it would make it much more economical to introduce RFBs in a large-scale grid storage role.  The synthesis, characterization and preliminary electrochemical investigation of these molecules will be described.

Andrew Rajewski

Andy also presented a poster at the Schaap Symposium…

Cyclopropenium Donors for Linked Donor-Acceptor Systems for Symmetric Nonaqueous Redox Flow Batteries

Andrew Rajewski, Adina Dumitrascu, Jason G. Gillmore, Thomas F. Guarr

A series of molecules containing electron donor (D) and electron acceptor (A) moieties are being explored for future use in symmetric organic redox flow batteries (RFBs).  The synthesis, characterization and preliminary electrochemical investigation of these molecules will be described.  Past studies in the group have looked at heterocyclic donors.  This work focuses on the synthesis of cyclopropenium donors for use in linked donor-acceptor systems.  Cyclopropenium donors have been studied in recent years and have shown promising properties for use in RFBs (>=0.8 V vs. Fc/Fc+, <3% loss of storage capacity over 200 cycles).)  Linking these donors to acceptors in linked systems allows for a symmetric RFB that eliminates the ubiquitous and expensive ion exchange membrane used in typical RFBs.  Because the membrane can account for up to 40% of cell costs, this could represent an important opportunity to improve the economics of employing flow batteries for grid-level energy storage applications.

  1. Sanford, Adv. Energy Mater., 2016 7(5), 1602027